One Hundred years ago today the first large scale use of chemical weapons occurred during World War One. Germany was in a precarious situation at this point in the war. It was deadlocked on two fronts and would be overwhelmed if the situation did not change. German could not overcome the entrenched armies of the French and British to the west and was pressed by large number of Russian armies to the east. On January 31, 1915 the German army experimented with a new weapon in the hopes of breaking the stalemate. Near Bolimov (in modern day central Poland) German artillery fired approximately 18,000 shells at Russian positions. But instead of high explosives the shells were filled with xylyl bromide. Each shell contained about seven pounds of the chemical and a small explosive charge to spread the substance. Xylyl bromide was similar to what we would call tear gas today. The attack had little effect as the cold weather froze the xylyl bromide solid and the shells did little more than spread a white harmless powder over the battlefield. It is likely the Russian soldiers were unaware that they had been subject to a chemical attack. But the attack did trigger a Russian counter attack and the ensuing battle resulted in 60,000 casualties on both side with only the use of conventional weapons.
It should be noted that this was not the first use of chemical weapons during the war. On the onset of the war the French issued grenades to its soldiers that contained ethyl bromoacetate, another tear gas like substance. It was use to almost no effect (it was reported to cause little more than sneezing fits) and after the French depleted their stocks of the grenades they did not manufacture more.
The use of “asphyxiating” weapons was prohibited by the Hague convention prior to the war (the prohibition of which all the major participants of the war had agreed to uphold). The French used ethyl bromoacetate with the argument that it did not result in suffocation, and thus not banned by the Hague convention. The Germans would repeat this explanation when using xylyl bromide. However, the Germans would cite the French use of ethyl bromoacetate as justification when it used more lethal chemical weapons later in the war.